WebNov 27, 2024 · Narcissistic chiral self-sorting prevailed in the assembly of molecular face-rotating polyhedra from a C3h building block 5,5,10,10,15,15-hexabutyl-truxene-2,7,12-tricarbaldehyde and racemic mixtures of 1,2-diamines. Out of 124 possible stereoisomers, a pair of racemic polyhedra dominated, wherein (1R,2R)-di … WebThese ligands self-assemble into dinuclear cyclic metallosupramolecular aggregates upon coordination to [(dppp)Pd(OTf) 2] in a highly diastereoselective manner, by heterochiral self-sorting in a chiral self …
Narcissistic chiral self-sorting of molecular face-rotating polyhedra ...
WebMay 2, 2014 · A "chirality driven self-sorting" strategy is introduced for the controlled supramolecular organization of donor (D) and acceptor (A) molecules in multicomponent assemblies and p-n nanostructures with controlled molecular-level organization are created. 47 Dual-Mode Chiral Self-Assembly of Cone-Shaped Subphthalocyanine Aromatics. WebFeb 9, 2024 · The chiral self-sorting supramolecular polymerization was precisely controlled with the addition of Ag +. The unique chiral self-sorting occurred because of the coexistence of R-L 1 with right-handed helicity and the [R-L 1 Ag] + complex with left-handed helicity. Thus, the present chiral self-sorting was induced by self-discrimination … polyploidie sympatrische artbildung
Chirality‐Driven Self‐Assembly of Discrete, Homochiral FeII2L3 …
WebJan 24, 2024 · Chiral monomers 1 and 2, carrying C4- and C3-symmetric bowl-shape peptidic macrocycle cores, respectively, undergo supramolecular polymerization in solution via van der Waals and hydrogen bonding… 57 Self-sorting chiral subcomponent rearrangement during crystallization. WebSelf-sorting strategies are suitable and effective approaches for accomplishing more complex rotaxanes and catenanes based on orthogonal binding motifs. ... and chiral self-sorting into homochiral or heterochiral complexes. 40. Jędrzejewska H. Szumna A. Making a right or left choice: chiral self-sorting as a tool for the formation of discrete ... WebMar 20, 2024 · Metal‐Induced Planar Chirality of Soft‐Bridged Binuclear Platinum (II) Complexes: 100% Phosphorescence Quantum Yields, Chiral Self‐Sorting, and Circularly Polarized Luminescence - Song - Angewandte Chemie International Edition - Wiley Online Library. Research Article. polyploidy in crop improvement