WebMay 13, 2024 · Abstract. In the present article, we use an improved Flory-Rehner theory to describe the swelling behavior of copolymer microgels, where the interaction parameter is modeled by a Hill-like equation for a cooperative thermotropic transition. This description leads to very good fits of the swelling curves of the copolymer microgels at different ... WebJul 18, 2016 · 正规溶液理论(regular so lut io Flory.Rehner方程来进行定量表征。已经证明,在没有明显的特异性反应发 间,溶解的自由能与聚合物分子的弹性恢复力(由聚合物链与链交联点之间的平均长度决定,Mc)应相等(Flory,1953;Sperling,1992),如果聚合物一溶剂间相 互作用热力 ...
Theoretical investigation of the swelling of polysaccharide microgels ...
WebWe therefore extend the classic Flory-Rehner theory of hydrogel swelling by coupling it to Hertzian contact mechanics that explicitly treats the stresses exerted by the medium at the hydrogel-grain contacts. Using this approach, we show that the extent of hydrogel swelling is determined by the balance between the osmotic swelling force exerted ... delaware servicept
高分子ゲルの拡張Flory-Rehnerモデルを用いた線形摂動解析
Web改性碳酸钙对γ射线交联三元乙丙橡胶力学性能的影响* 2015-06-11 许云书 徐光亮 WebThe swelling is shown as a ratio of volumes which is identical to 1/φ 2 which is the concentration of polymer in the swollen gel. Check your intuitions about the effect of the measure of "happiness" (the Flory-Huggins χ where 0.5 is starting to be unhappy) and the sizes of the polymer and solvent. The density of the polymer, ρ 2 play a minor ... WebFrenkel–Flory–Rehner方程之所以冠他的名字是来自他在1938年发表的论文 。这篇论文的题目特别像一本比较完整的高分子物理书,但实际上对于标题中的每一个话题,Frenkel都 … fenway script